N-(2-Chlorobenzoyl)benzenesulfonamide
نویسندگان
چکیده
The asymmetric unit of the title compound, C(13)H(10)ClNO(3)S, contains two independent mol-ecules, the chloro-phenyl ring of one of them being disordered over two orientations with occupancies of 0.836 (2) and 0.164 (2). In one of the independent mol-ecules, the sulfonyl-bound phenyl ring and the chloro-phenyl ring form dihedral angles of 87.3 (1) and 46.8 (1)°, respectively, with the -S-NH-C=O segment, while in the other mol-ecule the corresponding angles are 76.0 (1) and 39.6 (1)°. In the crystal, mol-ecules are linked into tetra-meric units by N-H⋯O hydrogen bonds.
منابع مشابه
N-(3-Chlorobenzoyl)benzenesulfonamide
In the crystal structure of the title compound, C(13)H(10)ClNO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. The dihedral angle between the two benzene rings is 87.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O(S) hydrogen bonds.
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In the structure of the title compound, C(13)H(9)Cl(2)NO(3)S, the N-H bond is anti to the C=O bond and the dihedral angle between the two aromatic rings is 76.9 (1)°. In the crystal structure, mol-ecules are linked by N-H⋯O(S) hydrogen bonds to form inversion dimers.
متن کامل4-Chloro-N-(2-chlorobenzoyl)benzenesulfonamide
In the structure of the title compound, C(13)H(9)Cl(2)NO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. The mol-ecule is twisted at the S atom with a torsion angle of 65.7 (2)°. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 88.5 (1)°, and that between the sulfonyl and the benzoyl benzene rings is 58.0 (1)°. I...
متن کاملN-(4-Chlorobenzoyl)benzenesulfonamide
In the crystal structure of the title compound, C(13)H(10)ClNO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. The dihedral angle between the two aromatic rings is 68.6 (1)°. The mol-ecule is twisted at the S atom with a dihedral angle of 75.7 (1)° between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment; the dihedral angle between the latter...
متن کامل2-Chloro-N-(4-chlorobenzoyl)benzenesulfonamide toluene hemisolvate
The unit cell of the title compound, C(13)H(9)Cl(2)NO(3)S·0.5C(7)H(8), contains two mol-ecules of 2-chloro-N-(4-chloro-benzo-yl)benzene-sulfonamide and one toluene mol-ecule, which is disordered about a centre of inversion. The dihedral angle between the two aromatic rings is 85.7 (1)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming centrosymmetric dimers.
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